BOILER

phosphate ion concentration in boiler water

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Water quality control of boiler Subject model: Auxiliary

Boiler water pH at 25 --- 11.0 - 11.8 10.5 - 11.5 Chloride ion concentration ppm 100 or less 50 or less Phosphate ion concentration ppm 20 - 100 20 - 40 Residual hydrazine (Residual DEHA in condensate) ppm 0.1 - 1.0 (0.12 - 0.30) *1: Continuous monitoring *2: Monitoring with observation tank or feed water filter tank

Marine Engineering: Boiler Water Testing

Dec 15, 2010 · Phosphate ppm Test (PO4) Purpose: 1.It helps to maintain a phosphate reserve in the boiler to counter any possible contamination of the boiler water by corrosive and scale forming salts. However, too much phosphate in the boiler may also contribute to foaming and priming. Procedures: 1.Take the comparator with the 10 ml cells provided.

Boiler water chemistry - Properties of feed water explored

Chloride ion. It also serves as a standard of boiler water concentration together with total solids. Formation of chloride ions can be done by controlling the amount and time of boiler blow down. Standard value of chloride ion is less than 300 mg Cl/l.

What is the concentration of phosphate which injecting in

What is the concentration of phosphate scuh as sodium hexametaphosphate are both used in steam boilers to precipitate whatever small amounts of calcium ion reach the boiler water through the

Determination of phosphate concentration in boiler water

The impossibility of unambiguously estimating phosphate concentration by measuring boiler-water conductivity in a high-pressure drum boiler ( p b = 13.8 MPa) is shown. Mathematical models of ion equilibria in boiler water, which allow one to determine the concentration of phosphates and other ion admixtures from the measurement data obtained with the use of standard (conductormeters and pH-meters) in cooled samples of feedwater and boiler water, are described.

Calculating Boiler Chemical Requirements Water Technology

Jun 26, 2017 · Assume boiler is operating at 10 cycles of concentration with feedwater at 205 o F. This equates to a dissolved oxygen content of 0.7 ppm or 0.5 cc per liter. This equates to a dissolved oxygen content of 0.7 ppm or 0.5 cc per liter.

METHODS FOR THE ANALYSIS OF BOILER WATER

depends on the P04= ion concentration. A number of reducing agents have been found suitable including Sn, SnCI 2, hydroquinone and 1-2-4 aminonaphthol sulphonic acid. The Sugar Millers Research Institute adapted the use of SnC1 2 for the determination of phosphate in mixed juices and their procedure has been found suitable for boiler waters.

Understand the importance of water/steam chemistry

Researchers were under the mistaken impression at the time that the sodium-to-phosphate ratio in the deposits generally remained within the 2.3 to 2.6 range, and thus by maintaining a sodium-to-phosphate ratio within this range in the bulk-boiler water, phosphate would precipitate "congruently" with the residual remaining in the bulk solution.

What is the concentration of phosphate which injecting in

What is the concentration of phosphate scuh as sodium hexametaphosphate are both used in steam boilers to precipitate whatever small amounts of calcium ion reach the boiler water through the

Internal treatment and control of boiler feed water | Hard

Jun 06, 2015 · Preventing foaming of boiler water; Neutralizing and film forming to prevent corrosion; Boiler water treatment chemicals and their functions. Phosphate base chemicals and alkali agent. Phosphate base boiler compounds for low-pressure boiler contain phosphates and alkali agents.

Plant Service Bulletin: Boiler Water Phosphate Chemistry

concentration of phosphate in the bulk boiler water can decrease with increasing load and pressure, and then return to the original levels on subsequent load or pressure reductions. This phenomenon, known as "phosphate hideout," can make it difficult to maintain close control of the pH phosphate concentration. Both

Boiler Water Treatment Chemicals, Feed, and Control - Perhaps

dosage to provide a feedwater or boiler water residual. Sodium Sulfite Example The reaction rate is: 2Na 2SO 3 (7.88 ppm) + O 2 ( 1 ppm) o 2Na 2SO 4 For the residual, 1.6 ppm Na 2SO 3 will yield 1 ppm SO 3. The total calculation equation to remove residual oxygen and provide a boiler water residual is:

Determination of phosphate concentration in boiler water

Jul 11, 2008 · The impossibility of unambiguously estimating phosphate concentration by measuring boiler-water conductivity in a high-pressure drum boiler (p b = 13.8 MPa) is shown. Mathematical models of ion equilibria in boiler water, which allow one to determine the concentration of phosphates and other ion admixtures from the measurement data obtained

Why is phosphate dosing done in a boiler? - Quora

The Function of Tri sodium Phosphate dosing in Boiler water is to condition feed water to ensure that plant involved in the steam / water cycle is kept free from corrosion. Tri sodium phosphate solution is to be dosed in Boiler Drum / HRSG Drums to maintain water PH, to minimize potential acid and caustic corrosion in the drums.

Phosphate test - Wikipedia

Quantitative methodEdit. This will produce a blue color (due to the formation of molybdenum blue) and the depth of the blue color indicates the amount of phosphate in the boiler water. The absorbance of the blue solution can be measured with a colorimeter and the concentration of phosphate in the original solution can be calculated.

Boiler water - Wikipedia

Acceptable phosphate concentrations decrease from 140 mg/L in low pressure boilers to less than 40 mg/L at pressures above 1,500 pounds per square inch (10,000 kPa). Recommended alkalinity similarly decreases from 700 mg/L to 200 mg/L over the same pressure range. Foaming problems are more common with high alkalinity.

What is the concentration of phosphate which injecting in

What is the concentration of phosphate scuh as sodium hexametaphosphate are both used in steam boilers to precipitate whatever small amounts of calcium ion reach the boiler water through the

Boiler Water Tests | Viking Water Technology, Inc.

May 04, 2016 · This can be accomplished only if the phosphate levels are correct and alkalinity/pH levels are correct. To assure that the calcium + phosphate reaction goes to completion, there must be at least 20 ppm excess phosphate in the boiler. If phosphate rises much over 60 ppm, it can contribute to boiler carryover.

Ph And Phosphate Concentration In Bfw And Steam Drum

Ph And Phosphate Concentration In Bfw And Steam Drum - posted in Industrial Professionals: Boiler feed water (BFW) pH is to be maintained in the range of 8.0 to 9.5(guidelines) where as in steam drum pH maintaining guidelines is in the range of 9.5 to 11.0. Pressure of steam drum is 34 barg.

CHAPTER 39 BOILER WATER TREATMENT

boiler water, calcium will preferentially precipitate as the phosphate before pre- cipitating as the carbonate, and calcium phosphate becomes the most prominent feature of the deposit.

Boiler Water Tests | Viking Water Technology, Inc.

May 04, 2016 · Chloride ions, unlike other ions that enter the boiler, are extremely soluble and do not precipitate or decompose when subjected to boiler conditions. Therefore, chlorides are used as a measure of boiler water concentrations (i.e. how many times the mineral contentwhich stays in the boiler when steam is producedof the raw water has been

Boiler Water Treatment Guidelines; Columbia Boiler Co

It is desirable to keep the concentration of phosphates in the water to 30 - 50 PPM in order for complete reaction of the phosphates with the calcium hardness entering the boiler through the feedwater. Hardness. The hardness of water is caused by calcium and magnesium ions which will vary greatly throughout the country depending on the source of the water. In boilers the hardness of the water can cause the formation of scale and sludge or mud.

What Is a Boiler Feed Water Treatment System and How Does It

Sep 26, 2016 · The most appropriate boiler feed water treatment system will help the facility avoid costly plant downtime, expensive maintenance fees, and boiler failure as a result of scaling, corrosion, and fouling of the boiler and downstream equipment. But what is a boiler feed water treatment system and how does it work?

A study of the influence of chloride ion concentration on the

Jan 11, 2008 · The main constituents of the oxidative films in the gas and liquid phases both were Fe3O4., In order to prevent carbon steel from corroding in boiler water containing Cl under conditions of lowphosphate and lowsodium hydroxide treatment, the concentration of Cl should be strictly controlled., It was found that the presence of excessive Cl in boiler water accelerated the corrosion of No. 20 carbon steel and the maximum permissible concentration of Cl under the

Determination of phosphate concentration in boiler water

The impossibility of unambiguously estimating phosphate concentration by measuring boiler-water conductivity in a high-pressure drum boiler (p b = 13.8 MPa) is shown.