Boiler water pH at 25 --- 11.0 - 11.8 10.5 - 11.5 Chloride ion concentration ppm 100 or less 50 or less Phosphate ion concentration ppm 20 - 100 20 - 40 Residual hydrazine (Residual DEHA in condensate) ppm 0.1 - 1.0 (0.12 - 0.30) *1: Continuous monitoring *2: Monitoring with observation tank or feed water filter tank
Learn MoreDec 15, 2010 · Phosphate ppm Test (PO4) Purpose: 1.It helps to maintain a phosphate reserve in the boiler to counter any possible contamination of the boiler water by corrosive and scale forming salts. However, too much phosphate in the boiler may also contribute to foaming and priming. Procedures: 1.Take the comparator with the 10 ml cells provided.
Learn MoreChloride ion. It also serves as a standard of boiler water concentration together with total solids. Formation of chloride ions can be done by controlling the amount and time of boiler blow down. Standard value of chloride ion is less than 300 mg Cl/l.
Learn MoreWhat is the concentration of phosphate scuh as sodium hexametaphosphate are both used in steam boilers to precipitate whatever small amounts of calcium ion reach the boiler water through the
Learn MoreThe impossibility of unambiguously estimating phosphate concentration by measuring boiler-water conductivity in a high-pressure drum boiler ( p b = 13.8 MPa) is shown. Mathematical models of ion equilibria in boiler water, which allow one to determine the concentration of phosphates and other ion admixtures from the measurement data obtained with the use of standard (conductormeters and pH-meters) in cooled samples of feedwater and boiler water, are described.
Learn MoreJun 26, 2017 · Assume boiler is operating at 10 cycles of concentration with feedwater at 205 o F. This equates to a dissolved oxygen content of 0.7 ppm or 0.5 cc per liter. This equates to a dissolved oxygen content of 0.7 ppm or 0.5 cc per liter.
Learn Moredepends on the P04= ion concentration. A number of reducing agents have been found suitable including Sn, SnCI 2, hydroquinone and 1-2-4 aminonaphthol sulphonic acid. The Sugar Millers Research Institute adapted the use of SnC1 2 for the determination of phosphate in mixed juices and their procedure has been found suitable for boiler waters.
Learn MoreResearchers were under the mistaken impression at the time that the sodium-to-phosphate ratio in the deposits generally remained within the 2.3 to 2.6 range, and thus by maintaining a sodium-to-phosphate ratio within this range in the bulk-boiler water, phosphate would precipitate "congruently" with the residual remaining in the bulk solution.
Learn MoreWhat is the concentration of phosphate scuh as sodium hexametaphosphate are both used in steam boilers to precipitate whatever small amounts of calcium ion reach the boiler water through the
Learn MoreJun 06, 2015 · Preventing foaming of boiler water; Neutralizing and film forming to prevent corrosion; Boiler water treatment chemicals and their functions. Phosphate base chemicals and alkali agent. Phosphate base boiler compounds for low-pressure boiler contain phosphates and alkali agents.
Learn Moreconcentration of phosphate in the bulk boiler water can decrease with increasing load and pressure, and then return to the original levels on subsequent load or pressure reductions. This phenomenon, known as "phosphate hideout," can make it difficult to maintain close control of the pH phosphate concentration. Both
Learn Moredosage to provide a feedwater or boiler water residual. Sodium Sulfite Example The reaction rate is: 2Na 2SO 3 (7.88 ppm) + O 2 ( 1 ppm) o 2Na 2SO 4 For the residual, 1.6 ppm Na 2SO 3 will yield 1 ppm SO 3. The total calculation equation to remove residual oxygen and provide a boiler water residual is:
Learn MoreJul 11, 2008 · The impossibility of unambiguously estimating phosphate concentration by measuring boiler-water conductivity in a high-pressure drum boiler (p b = 13.8 MPa) is shown. Mathematical models of ion equilibria in boiler water, which allow one to determine the concentration of phosphates and other ion admixtures from the measurement data obtained
Learn MoreThe Function of Tri sodium Phosphate dosing in Boiler water is to condition feed water to ensure that plant involved in the steam / water cycle is kept free from corrosion. Tri sodium phosphate solution is to be dosed in Boiler Drum / HRSG Drums to maintain water PH, to minimize potential acid and caustic corrosion in the drums.
Learn MoreQuantitative methodEdit. This will produce a blue color (due to the formation of molybdenum blue) and the depth of the blue color indicates the amount of phosphate in the boiler water. The absorbance of the blue solution can be measured with a colorimeter and the concentration of phosphate in the original solution can be calculated.
Learn MoreAcceptable phosphate concentrations decrease from 140 mg/L in low pressure boilers to less than 40 mg/L at pressures above 1,500 pounds per square inch (10,000 kPa). Recommended alkalinity similarly decreases from 700 mg/L to 200 mg/L over the same pressure range. Foaming problems are more common with high alkalinity.
Learn MoreWhat is the concentration of phosphate scuh as sodium hexametaphosphate are both used in steam boilers to precipitate whatever small amounts of calcium ion reach the boiler water through the
Learn MoreMay 04, 2016 · This can be accomplished only if the phosphate levels are correct and alkalinity/pH levels are correct. To assure that the calcium + phosphate reaction goes to completion, there must be at least 20 ppm excess phosphate in the boiler. If phosphate rises much over 60 ppm, it can contribute to boiler carryover.
Learn MorePh And Phosphate Concentration In Bfw And Steam Drum - posted in Industrial Professionals: Boiler feed water (BFW) pH is to be maintained in the range of 8.0 to 9.5(guidelines) where as in steam drum pH maintaining guidelines is in the range of 9.5 to 11.0. Pressure of steam drum is 34 barg.
Learn Moreboiler water, calcium will preferentially precipitate as the phosphate before pre- cipitating as the carbonate, and calcium phosphate becomes the most prominent feature of the deposit.
Learn MoreMay 04, 2016 · Chloride ions, unlike other ions that enter the boiler, are extremely soluble and do not precipitate or decompose when subjected to boiler conditions. Therefore, chlorides are used as a measure of boiler water concentrations (i.e. how many times the mineral contentwhich stays in the boiler when steam is producedof the raw water has been
Learn MoreIt is desirable to keep the concentration of phosphates in the water to 30 - 50 PPM in order for complete reaction of the phosphates with the calcium hardness entering the boiler through the feedwater. Hardness. The hardness of water is caused by calcium and magnesium ions which will vary greatly throughout the country depending on the source of the water. In boilers the hardness of the water can cause the formation of scale and sludge or mud.
Learn MoreSep 26, 2016 · The most appropriate boiler feed water treatment system will help the facility avoid costly plant downtime, expensive maintenance fees, and boiler failure as a result of scaling, corrosion, and fouling of the boiler and downstream equipment. But what is a boiler feed water treatment system and how does it work?
Learn MoreJan 11, 2008 · The main constituents of the oxidative films in the gas and liquid phases both were Fe3O4., In order to prevent carbon steel from corroding in boiler water containing Cl under conditions of lowphosphate and lowsodium hydroxide treatment, the concentration of Cl should be strictly controlled., It was found that the presence of excessive Cl in boiler water accelerated the corrosion of No. 20 carbon steel and the maximum permissible concentration of Cl under the
Learn MoreThe impossibility of unambiguously estimating phosphate concentration by measuring boiler-water conductivity in a high-pressure drum boiler (p b = 13.8 MPa) is shown.
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